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Rate-equilibrium correlation for dissociation of a carbon acid

โœ Scribed by R. Stewart; J.P. O'Donnell; D.J. Cram; B. Rickborn


Book ID
108373952
Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
532 KB
Volume
18
Category
Article
ISSN
0040-4020

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A generalized rate law for the thermal d
โœ Heshel Teitelbaum ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 256 KB

It is shown that the standard rate law for thermal decomposition of diatomic molecules, AB, in mixtures with an inert species, M, breaks down severely under conditions of vibrational disequilibrium, even when the time scales for relaxation and dissociation