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Rate-Determining Step in the Electrogenerated Chemiluminescence from Tertiary Amines with Tris(2,2‘-bipyridyl)ruthenium(II)

✍ Scribed by Wightman, R. Mark; Forry, Samuel P.; Maus, Russell; Badocco, Denis; Pastore, Paolo


Book ID
126201741
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
90 KB
Volume
108
Category
Article
ISSN
0022-3654

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## Abstract A capillary electrophoresis with electrogenerated chemiluminescence (CE–ECL) method for the determination of trimethylamine (TMA) in fish was studied. In the presence of TMA, ECL from the reaction of analyte and __in situ__ generated tris(2,2′‐bipyridyl)ruthenium(III) [Ru(bpy)~3~^3+^] a