The gas-phase reaction of NO 3 radicals with selected oxiranes has been studied in a flow system at T = 295 + 2 K in the pressure range 3.4-50 mbar using N 2 as carrier gas. The analysis of the organics was performed by means of on-line connected GC-FID. Rate constants were obtained with the relativ
Rate constants of the reaction of cumyl peroxide radicals with 2-arylindan-1, 3-diones
✍ Scribed by A. B. Gagarina; L. M. Pisarenko; V. V. Moiseev; N. M. Émanuél'
- Book ID
- 112438124
- Publisher
- Springer
- Year
- 1975
- Tongue
- English
- Weight
- 418 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The rate constants for the reaction of OH radicals with a series of 1 chloroalkanes were measured at 295 K and at a total pressure of 1 atm. The rate constants were obtained by using the absolute technique of pulse radiolysis combined with kinetic UV-spectroscopy. The results are discussed in terms
An electron paramagnetic resonance (EPR) technique was used to show that simple alkyl radicals readily abstract hydrogen from l,4-cyclohexadiene. Rate constants for the reaction were ca. 104-105 M-' s-' at 300 K and activation energies 5-7 kcal mol-'. For the stabilized radicals, ally1 and benzyl, t