Rate constants of substantial initiation in free-radical polymerization: A new method for determination of conversion dependences
β Scribed by G. V. Korolev; M. P. Berezin; V. P. Grachev
- Book ID
- 111469064
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2007
- Tongue
- English
- Weight
- 202 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1560-0904
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π SIMILAR VOLUMES
A relatively fast method for determining the initial rate of polymerization from the maximum of isothermal thermograms ("Vp. max method") is described. The method was verified for the polymerization of methyl methacrylate in dimethylformamide. The initial rates and overall rate constants agree excel
## Abstract Pulsed laser polymerization (PLP) in conjunction with online size exclusion chromatography β electrospray ionization mass spectrometry (SEC/ESIβMS) has successfully been applied for the determination of accurate propagation rate coefficients, __k__~p~, in free radical polymerization. SE