A method is described for the measurement of relative rate constants for abstraction of hydrogen from ethylene at temperatures in the region of 750 K. The method is based on the effect of the addition of small quantities of propane and isobutane on the rates of formation of products in the thermal c
Rate constants of hydrogen abstraction by methyl radical from n-butanol and a comparison of CanTherm, MultiWell and Variflex
โ Scribed by Katsikadakos, D.; Zhou, C.-W.; Simmie, J.M.; Curran, H.J.; Hunt, P.A.; Hardalupas, Y.; Taylor, A.M.K.P.
- Book ID
- 118004983
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 474 KB
- Volume
- 34
- Category
- Article
- ISSN
- 1540-7489
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๐ SIMILAR VOLUMES
The rate constant for abstraction of hydrogen from isobutane by methyl radicals has been re-examined making use of new measurements at temperatures above 660 K. Most of the data over the temperature range 300-855 K can be accommodated by the following values for the rate constants for abstraction fr
Measurements rate constants for abstraction of hydrogen from ethylene by methyl and ethyl radicals relative to the corresponding rate constants for abstraction from hydrogen, over the temperature range 650-770 K, are reported. The method is based on the effect of the addition of small quantities of