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Rate Constants in Free Radical Polymerizations. IV. Methyl Acrylate 1

โœ Scribed by Matheson, Max S.; Auer, E. E.; Bevilacqua, Ellen B.; Hart, E. J.

Book ID
126948531
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
831 KB
Volume
73
Category
Article
ISSN
0002-7863

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Desorption of free radicals in semibatch
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โœ C. S. Chern ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 618 KB

Desorption of free radicals from particles can cause an emulsion polymerization system to deviate from Smith-Ewart case I1 kinetics. A mechanistic model has been developed to predict the effect of desorption of radicals from particles on the kinetics of semibatch emulsion polymerization of methyl ac