Rate Constants for the Reaction of the Carbonate Radical with Compounds of Biochemical Interest in Neutral Aqueous Solution
โ Scribed by Chen, Schoen-nan; Hoffman, Morton Z.
- Book ID
- 120231501
- Publisher
- Bioone
- Year
- 1973
- Tongue
- English
- Weight
- 288 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0033-7587
- DOI
- 10.2307/3573789
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๐ SIMILAR VOLUMES
## Abstract The kinetics of the oxidation of functionalized organic compounds of atmospheric relevance by the hydroxyl radical (OH) was measured in the aqueous phase. Competition kinetics, using the thiocyanate anion (SCN^โ^) as competitor, was applied using both a laser flash photolysis long path
The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.