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Rate constants for the gas phase reactions of the OH radical with CF 3 CF 2 CHCl 2 (HCFC-225ca) and CF 2 ClCF 2 CHClF (HCFC-225cb)

✍ Scribed by Zhang, Zhengyu; Liu, Renzhang; Huie, Robert E.; Kurylo, Michael J.

Book ID: 119684548
Publisher: American Geophysical Union
Year: 1991
Tongue: English
Weight: 252 KB
Volume: 18
Category: Article
ISSN: 1944-8007
DOI: 10.1029/90gl02647

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Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21