## Abstract Relative rate constants for the reaction of OH radicals with a series of ketones have been determined at 299 ± 2 K, using methyl nitrite photolysis in air as a source of hydroxyl radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 × 10^−12^ cm^3^ mol
Rate Constants for the Gas-Phase Reactions of OH Radicals with a Series of C 6 −C 14 Alkenes at 299 ± 2 K
✍ Scribed by Nishino, Noriko; Arey, Janet; Atkinson, Roger
- Book ID
- 121402568
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 142 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
## Abstract Using methyl nitrite photolysis in air as a source of hydroxyl radicals, relative rate constants for the reaction of OH radicals with a series of alkanes and alkenes have been determined at 299 ± 2 K. The rate constant ratios obtained are: relative to __n__‐hexane = 1.00, neopentane 0.1
By using relative rate methods, rate constants for the gas-phase reactions of OH and NO 3 radicals with propanal, butanal, pentanal, and hexanal have been measured at 296 Ϯ 2 K and atmospheric pressure of air. By using methyl vinyl ketone as the reference compound, the rate constants obtained for th
Relative rate constants for the gas-phase reactions of OH radicals with a series of bi-and tricyclic alkanes have been determined at 299 f 2 K, using methyl nitrite photolysis in air as a source of OH radicals. Using a rate constant for the reaction of OH radicals with cyclohexane of 7.57 X cm3/mole