## Abstract Using methyl nitrite photolysis in air as a source of hydroxyl radicals, relative rate constants for the reaction of OH radicals with a series of alkanes and alkenes have been determined at 299 ± 2 K. The rate constant ratios obtained are: relative to __n__‐hexane = 1.00, neopentane 0.1
Relative rate constants for the reaction of OH radicals with selected C6 and C7 alkanes and alkenes at 305 ± 2 K
✍ Scribed by Karen R. Darnall; Arthur M. Winer; Alan C. Lloyd; James N. Pitts Jr.
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 442 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Using a relative rate technique, rate constants for the gas phase reactions of the OH radical with n-butane, n-hexane, and a series of alkenes and dialkenes, relative to that for propene, have been determined in one atmosphere of air at 295 f 1 K. The rate constant ratios obtained were (propene = 1.
Relative rate constants for the gas-phase reactions of C1-atom with thirteen atmospherically interesting alkanes ( c 2 -C ~) have been determined at 296 i-2 K based on GC/FID measurements of their relative decays in the UV (A 2 300 nm) photolysis of mixtures containing Cl2 and the entire series of t
The absolute rate constants for the gas-phase H-atom abstraction by hydroxyl radicals from cyclohexane and ethane have been determined at room temperature. OH radicals were produced by pulse radiolysis of an H,O-Ar mixture, and the decay of OH was followed by monitoring the transient light absorpti
Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with the three cresols and the six dimethylphenols have been determined a t 296 t 2 K and atmospheric pressure. The rate constants for the cresols, which range from 4.3 x lo-" cm3 molecule-' s-' to 6.8 x lo