The gas-phase reaction of bornyl acetate (bicyclo[2,2,1]-heptan-2-ol-1,7,7-trimethyl-acetate) with hydroxyl radical has been studied. A relative method was used to determine the rate constant for this reaction, with n-octane as reference compound. Methyl nitrite photolysis experiments were carried
Rate constants for the gas phase reactions of O3 with the natural hydrocarbons isoprene and α- and β-pinene
✍ Scribed by R. Atkinson; A.M. Winer; J.N. Pitts Jr.
- Book ID
- 113121459
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 392 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0004-6981
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## Abstract Rate constants for the gas‐phase reactions of the hydroxyl radical with the biogenic hydrocarbons, β‐myrcene and isoprene, were measured using the relative rate technique over the temperature range 313–413 K and at ∼1 atm total pressure. OH was produced by the photolysis of H~2~O~2~, an
## Abstract Rate constants for the gas‐phase reactions of O~3~ with ethene, propene, 1‐hexene, 1‐heptene, styrene, __o__‐, __m__‐, and __p__‐cresol, __o__‐ and __m__‐xylene, benzylchloride, acrylonitrile, and trichloroethene have been determined at 296 ± 2 K. The rate constants ranged from <5 × 10^
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## Abstract The reactions of the biogenic organic compounds isoprene and 2‐methyl‐3‐buten‐2‐ol (MBO) with ozone have been investigated under controlled conditions for pressure (atmospheric pressure) and temperature (293 ± 2 K), using FTIR spectrometry. CO was added to scavenge hydroxyl radical form