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Rate constants for some oxidations of S(IV) by radicals in aqueous solutions

โœ Scribed by Robert E. Huie; P. Neta

Book ID
113122966
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
684 KB
Volume
21
Category
Article
ISSN
0004-6981

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๐Ÿ“œ SIMILAR VOLUMES

Rate constants for one-electron oxidatio
Rate constants for one-electron oxidation by methylperoxyl radicals in aqueous solutions
โœ Robert E. HUIE; P. NETA ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 336 KB ๐Ÿ‘ 1 views

Rate constants for one-electron oxidation by the methylperoxyl radicals (CH302, HOCHzO;, -O2CCHz0;, and CClsO;) in aqueous solutions have been measured by pulse radiolysis and found to be in the range of 3 x lo5 to 6 x lo8 M-' sK1 for compounds with redox potentials between 0.6 and 0.1 V. Substituti

Rate constants for some reactions of fre
Rate constants for some reactions of free radicals with haloacetates in aqueous solution
โœ Pichai Maruthamuthu; S. Padmaja; Robert E. Huie ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 443 KB ๐Ÿ‘ 1 views

The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.

Temperature dependence of the self-decay
Temperature dependence of the self-decay rate constants of some phenoxyl radicals in aqueous solution
โœ Z. B. Alfassi; L. C. T. Shoute ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 728 KB

The Arrhenius parameters of the bimolecular rate constants for the decay of several phenoxyl radicals in aqueous solution were measured. The p-halophenoxyl radicals (F, C1, and Br) decay in a diffusion controlled reaction as the activation energies are the same as that of diffusion of water (16 ? 1.