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Rate Constants for Reactions of Phenoxyl Radicals in Solution

โœ Scribed by Neta, Pedatsur

Book ID
120446370
Publisher
American Institute of Physics
Year
2005
Tongue
English
Weight
611 KB
Volume
34
Category
Article
ISSN
0047-2689

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๐Ÿ“œ SIMILAR VOLUMES

Temperature dependence of the self-decay
Temperature dependence of the self-decay rate constants of some phenoxyl radicals in aqueous solution
โœ Z. B. Alfassi; L. C. T. Shoute ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 728 KB

The Arrhenius parameters of the bimolecular rate constants for the decay of several phenoxyl radicals in aqueous solution were measured. The p-halophenoxyl radicals (F, C1, and Br) decay in a diffusion controlled reaction as the activation energies are the same as that of diffusion of water (16 ? 1.

Rate constants for some reactions of fre
Rate constants for some reactions of free radicals with haloacetates in aqueous solution
โœ Pichai Maruthamuthu; S. Padmaja; Robert E. Huie ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 443 KB ๐Ÿ‘ 1 views

The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.