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Rate constants for ozone formation and for isotopic exchange reactions

โœ Scribed by Allan Gross; G.D. Billing


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
883 KB
Volume
173
Category
Article
ISSN
0301-0104

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๐Ÿ“œ SIMILAR VOLUMES


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## Abstract By measuring the rates of decay of ozone in a large excess of reactant, secondโ€order rate constants have been obtained for the reactions of ozone with ethene, propene, butโ€1โ€ene, __trans__โ€butโ€2โ€ene, isobutene, hexโ€1โ€ene, cyclopentene, cyclohexene, isoprene, vinyl fluoride, 1,1โ€difluoro

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Kcccivcd 7 hlarch 1977 The rate constant Ior the rrnction Br + 0~ -BrO + 02 has been mcawrcd over the tempcraturc rdrye 224 to 522 EC in a dxhargc llow systcni ucmk a IKISF spcctrornctcr a~ B detector. Rcsultg, c\pre%scd in the form kr = (3.34 c O-40) X IO-\*' X cxp[ -(978 1. 36)/T] cn13 s-' , arc c

Rate constants for the gas-phase reactio
โœ Eric Grosjean; Daniel Grosjean ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 431 KB ๐Ÿ‘ 1 views

The gas-phase reaction of ozone with unsaturated alcohols in air has been investigated a t atmospheric pressure and ambient temperature (288-291 K). Cyclohexane was added to scavenge the hydroxyl radical which forms as a product of the ozone-unsaturated alcohol reaction. The reaction rate constants,

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The kinetics of the gas-phase reaction of ozone with unsaturated alcohols, carbonyls, and esters in air have been investigated at atmospheric pressure, ambient temperature (285-295 K), and in the presence of sufficient cyclohexane to scavenge the hydroxyl radical which forms as a product of the ozon

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The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ฯญ 1 constants, in units of cm 3 molecule ฯช1 s ฯช1 , are for 2 (5H)-furanone, ฯช18 10 0.22 ฯฎ 0.05 for methacrolein, for crotonaldehyde, f

Rate constants for the reactions of meth
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Rate constants for the reaction of ozone with methylvinyl ketone (H 2 C " CHC(O)CH 3 ), methacrolein (H 2 C" C(CH 3 )CHO), methacrylic acid (H 2 C "C(CH 3 )C(O)OH), and acrylic acid (H 2 C " CHC(O)OH) were measured at room temperature in the pres-(296 ฯฎ 2 K) ence of a sufficient amount of cyclohexan