Rate constant for the reaction of nitrogen dioxide with sulfur(IV) over the pH range 5.3-13
โ Scribed by Clifton, Carol L.; Altstein, Nisan.; Huie, Robert E.
- Book ID
- 126951795
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 460 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0013-936X
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๐ SIMILAR VOLUMES
Rate constants for the reaction between Cl atoms and HOh'02 were measured at 243,264. and 198 I( by the flash photolysis resonance fluorescence technique\_ The data can be fit to the Arrhenius expression R1 = 5.1 X lo-" esp(-1700/T) cm3 m01ecule~~ s-' snd indicate that the reaction is unimportanr in
Rate constants for the reaction of OH radicals vlith COS. CSz and CII~SCHJ, which are invo!ved in the glohal sulfur cycle, iI;IVC been determined over the temperature range 299-430 K uGng a flash ps hotolysis-resonance fluorcsccnu: tcchmque. For COS and CS2 upper limits at room tcmyzraturc of k(COS)
Absolute rate constants. k2. for the reaction of OH radicals with 2-methyl-2-butene have been determined over the temperature range 297-425 K usinp P flash photolysis-resonance fluorescence technique. The Arrhenius expression obtained was & = 3.6 X lo-" exp [(450 +-400)/RTJ cm3 moleculeS1 ~8.