✦ LIBER ✦

Rate constant for the reaction of nh2 with ozone in relation to atmospheric processes

✍ Scribed by H. Kurasawa; R. Lesclaux

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 592 KB
Volume: 72
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80325-3

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✦ Synopsis

The absolute rate constant of the reaction between NH2 and ozone has been measured using a flash photo&is--laser resonance techmque and found to be 4 = 6.3 (~1.0) X IO-l4 cm3 molecule-' S-I at room temperature. The &hen&s expressIon, determined from measurements in the temperature range 298-380 K IS k4 = 4.2 X lO-L2 exp(-2.5 = OS/RI) (E III kcal mole-' ). The possiihty of formation or ehrmnatlon of nitrogen oxides from the reactions of NH2 in the atmosphere E exarnmed.

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