Rate constant for the reaction of chromium(II) with vanadium(IV). A competition study
โ Scribed by Bakac, Andreja.; Espenson, James H.
- Book ID
- 120533250
- Publisher
- American Chemical Society
- Year
- 1981
- Tongue
- English
- Weight
- 241 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The rate constant for the reaction of CI with CHCI, was measured relative to the CI reaction with Cti, and CH,CI using long path FTIR. The measured rate constant at 298 K and 1 atm total pressure was ( I 21 ? 0 13) X 10-"cm3 molecule-'s-' ( 2 ~1 , about 60%larger than the currently recommended value
Rate constants for the gas phase reactions of CC1 generated by the flash photolysis of CHBrzCl with a series of silanes have been obtained by kinetic absorption spectroscopy. In general, the rate constants arc very high, and range fmm (4 8 2 0.5) X 10' (SIHH~) to (6-4 r 0.34) % IO9 for SitHe. CC1 do
The reaction involves two short-lived collision complexes, BHNOf and HBONt, which rearrange to products BO+NH via the same cyclic transition state. The overall rate constant depends on the rates of complex formation by capture over the centrifugal barrier in the dipole-dipole potential, and the rate