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Rate constant for deuterium atom recombination calculated by the orbiting resonance theory

✍ Scribed by R.E. Roberts; R.B. Bernstein

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 230 KB
Volume: 6
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)85075-8

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✦ Synopsis

The resonance theory of termolecular recombination kinetics is applied to the reaction D + D + D2 + 2D2. The isotope effect. i,e.. the rate of deuterium recombination compared to that of hydrogen. is computed over the range SO-300°R. From 100° to room temperature the ratio for D/H is O_7l (*O.OZ), in agreement with the experimental value of Amdur ( 1935) and a very recent determination by Kaufman. Ham and Trainar.

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