The rate constant of the reaction between OH and OCS in helium over the temperature range 255-483 K has been determined using the discharge flow-resonance fluorescence technique. The OCS has been carefully purified to avoid interference from HgS and CO impurities. An FTIR with a multireflection cell
Rate Constant and Mechanism of the Reaction of OH Radicals with Acetic Acid in the Temperature Range of 229−300 K
✍ Scribed by Butkovskaya, N. I.; Kukui, A.; Pouvesle, N.; Le Bras, G.
- Book ID
- 126984430
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 83 KB
- Volume
- 108
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Rate constants for the reaction between Cl atoms and HOh'02 were measured at 243,264. and 198 I( by the flash photolysis resonance fluorescence technique\_ The data can be fit to the Arrhenius expression R1 = 5.1 X lo-" esp(-1700/T) cm3 m01ecule~~ s-' snd indicate that the reaction is unimportanr in
Absolute rate constants. k2. for the reaction of OH radicals with 2-methyl-2-butene have been determined over the temperature range 297-425 K usinp P flash photolysis-resonance fluorescence technique. The Arrhenius expression obtained was & = 3.6 X lo-" exp [(450 +-400)/RTJ cm3 moleculeS1 ~8.
By using a relative rate technique, the rate constant for the gas phase reaction of OH radicals with diacetylene, a reaction considered to be of importance in fuel-rich acetylene oxidation, has been determined at 297 :t: 2K and atmospheric pressure. On the basis of a rate constant for the reaction o
The temperature dependency of the rate constants for the gas phase reaction of OH radicals with a series of chloroalkanes was measured in the temperature range from 295 to 360 K at a total pressure of I atm. The rate constants were obtained by using the absolute technique of pulse radiolysis combine
The rate constants of the gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3) over the temperature range 260-393 K have been studied using the discharge flow-resonance fluorescence technique. The rate constants were fitted by the Arrhenius equation k = (11.8 2 2.2) x exp[-(236 2 150)/T