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Rate coefficient measurements for reactions between uracil and N(2D0) atoms

โœ Scribed by K.K. Ghosh


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
293 KB
Volume
114
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Rate coefklenrs

of the reactions between uranl molecules and excited nltrosn atoms (N(ZDo)) have been measured at room temperature usmg the dynamic nowing afterglow method The measured rate coefficients are 3 3 and 2 7 X lO_"

cm3 5-l


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The rate constants k,, k2 and t for the reactions of N( 'D) atoms with I-I>, HF, and 02, measured at room temperature in a discharge-flow atomic-resonance-absorption apparatus, have been determined to be (1.8 kO.8) x IO-'\*, (1.0\_+0.3) x lo-'" and (6.6 f 1.0) X lo-l2 cm3 s-l, respectively. Previous

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Rate coefficients, in units of 10-~0 cm 3 molecule-~ s-~, for the O(~D) reactions with H2, D 2 and HD at 298 K were determined to be 1.2 \_\_\_ 0.1, 1.1 + 0.1, and 1.2 + 0.1, respectively. The H atom yield in the O(~ D) + HD reaction, relative to that in the O(ID) + H 2 reaction, was measured to be

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