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Rapid microwave-assisted preparation of amino-functionalized polymers

✍ Scribed by Natalie Ljungdahl; Laura Martikainen; Nina Kann

Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
257 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis

Two different methods for the rapid microwave-assisted amination of halide-functionalized polymers were investigated. Nucleophilic substitution by phthalimide, followed by ring opening with methylamine to liberate the free amine, afforded amino-substituted polymers with up to 76% conversion. The second method involves nucleophilic substitution with azide ions and subsequent treatment with triphenylphosphine. The latter method was found to be more efficient, with up to 99% conversion in favourable cases and with a reaction time of 2 Γ‚ 30 min.

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