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Raman spectra of gases: 23-Trichloroacetaldehyde

✍ Scribed by J. R. Durig; W. J. Natter

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
268 KB
Volume
11
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

The Raman spectrum of gaseous trichloroacetaldehyde (chloral) has been recorded from 20 to 3200 cm^−1^. A series of three transitions (83, 76, 69 cm^−1^) has been observed for the low frequency torsional mode. The barrier to internal rotation has been calculated to have a value of 1.17 kcal mol^−1^ (409 cm^−1^) in the gaseous phase. This value is compared to the corresponding quantity in similar molecules.

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