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Raman spectra of endohedral fullerenes. Li+ @C60

✍ Scribed by C.G. Joslin; C.G. Gray; S. Goldman; J. Yang; J.D. Poll

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 606 KB
Volume: 215
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)89278-p

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✦ Synopsis

The inelastic depolarized light-scattering spectrum of the endohedral metallofullerene Li+@& is calculated for frequency shifts up to 1000 cm-'. In this species the motion of the charged inclusion within the buckyball cage generates an induced anisotropic polarisability through an interesting mechanism involving the hyperpolarizability B. The resulting Raman spectrum is quite intense. At room temperature, hot bands contribute significantly to the scattering.

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