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Free and hindered rotations in endohedral C60 fullerene complexes

✍ Scribed by J. Hernández-Rojas; A. Ruiz; J. Bretón; J. M. Gomez Llorente

Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
207 KB
Volume
65
Category
Article
ISSN
0020-7608

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✦ Synopsis

We propose a two-parameter model Hamiltonian to analyze the lowenergy dynamics of endohedral C fullerene complexes such as Li q @C , Na q @C ,

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Electron Paramagnetic Resonance Investigation of Endohedral Fullerenes N@C60 and N@C70 in a Liquid Crystal
✍ P. Jakes; N. Weiden; R.-A. Eichel; A. Gembus; K.-P. Dinse; C. Meyer; W. Harneit; 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 118 KB

Endohedral fullerenes N@C(60) and N@C(70) were dissolved in the liquid crystal 4-methoxybenzylidene-4'-n-butylaniline (MBBA) and investigated by electron paramagnetic resonance. In both cases well resolved EPR spectra give proof for molecular orientation in the nematic mesophase. Spectral features a

Bonding in Endohedral Metal–Fullerene Co
Bonding in Endohedral Metal–Fullerene Complexes: f-Orbital Covalency in Ce@C28
✍ Prof. Dr. Notker Rösch; Dipl.-Phys. Oliver D. Häberlen; Dr. Brett I. Dunlap 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 422 KB

Three conditions must be met if an endohedral metal–fullerene complex is to be stable : 1. Metal valence orbitals and fullerene frontier orbitals must have complementary symmetry. 2. The metal atomic orbitals must fit inside the fullerene cavity. 3. The resulting complex must have a closed‐shell con