Raman phonon spectroscopy of solid-state reactions: thermal rearrangement of methyl p-dimethylaminobenzenesulfonate in solid state
β Scribed by Dwarakanath, Kaddi; Prasad, Paras N.
- Book ID
- 126286839
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 349 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The kinetic behaviour of the solid state thermal decomposition of dithionate to sulphate, M2[Sz0,] + M,[SO,], M = Na, K, has been studied by following the temporal decrease in the intensity of the Raman band arising from the v,(SO,) mode of [S2O6]". The sodium salt displays first order kinetics, but
AbstractΓ2,4,6-Trimethoxy-1,3,5-triazine 11, and 6-methoxy-3,5-dimethyl-tetrahydrotriazine-2,4-dione 13 undergo intermolecular O3N methyl rearrangement in the liquid-state to 1,3,5-trimethyl 2,4,6-trioxohexahydro-s-triazine 14. 4,6-Dimethoxy-3-methyl-dihydro-triazine-2-one 12 was found to exhibit a