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Radiochemical studies of free radical vinyl polymerization—V. Polymerization of methacrylonitrile in dimethylsulphoxide solution

✍ Scribed by G. Ayrey; B.C. Head; D.J.D. Wong

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
320 KB
Volume
10
Category
Article
ISSN
0014-3057

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✦ Synopsis

14

C]-Azoisobutyronitrile was used to initiate free radical polymerization of methacrylonitriIe at 60° in dimethylsulphoxide solution. Approximately two initiator fragments were found combined with each polymer molecule, indicating that termination was almost exclusively by combination of pairs of polymer radicals.

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The branched structure formation during free radical polymerization of vinyl acetate is investigated in detail by application of the computer simulations on the basis of the Monte Carlo sampling technique. Simulations are made for the whole molecular weight distribution (MWD), the MWDs for polymer m