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Radiochemical Investigation of the Coordination State of Iron in the Dinuclear Iron(III)-1,10-Phenanthroline Complex Ion

✍ Scribed by Priv.-Doz. Dr. P. Gütlich; B. W. Fitzsimmons


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
125 KB
Volume
8
Category
Article
ISSN
0044-8249

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Effect of cosolvent on the volume of act
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The kinetics of the base hydrolysis of Fe(phen) 3 2ϩ and Fe(bipy) 3 2ϩ (phen ϭ 1,10phenanthroline and bipy ϭ 2,2'-bipyridine) in some aqueous alcohol mixtures at ambient and elevated pressures (up to 1kbar) have been monitored spectrophotometrically at 25.0ЊC. For a given pressure, the alcohol cosol