Radio Frequency Magnetic Field Effects on a Radical Recombination Reaction: A Diagnostic Test for the Radical Pair Mechanism
โ Scribed by Henbest, Kevin B.; Kukura, Philipp; Rodgers, Christopher T.; Hore, P. J.; Timmel, Christiane R.
- Book ID
- 120507657
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 85 KB
- Volume
- 126
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Photochemical primary process and magnetic field effect of methyltriphenyl germane in a micelle have been investigated with the aid of a nanosecond laser-flash-photolysis technique. The germyl radical generated through triplet state was directly observed. The lifetime of the generated radical pair a
ExpressIons for a resonance dependence of gemmate recombmation probabhty of radical pairs on the intensity of an external steady magnetic field m the presence of a tigh-frequency magnetic field normal to it have been obtamed
The nonadiabatic ST\_ transitions induced by the fluctuating (anisotropic) part of the hyperfine and Zeeman interactions are shown to make a significant contribution to the magnetic field effects in the radical pair recombination in liquids and micelles. The anisotropic Zeeman interaction induced ST