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Radico-catalysis: possible involvement of a cobalt(II) complex in the free radical reactions of sulfur functions

✍ Scribed by Masaru Tada

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 142 KB
Volume: 12
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.1033

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✦ Synopsis

Abstract

A cobalt(II) complex is paramagnetic and can be coordinated with sulfur functions; the coordination complex delocalizes an unpaired electron from cobalt(II) to the sulfur functions such as thioester and vinyl sulfide. Thus, the generation of partial unpaired electron density on the sulfur functions induces or modifies the reactions of the organo free radical containing the sulfur function. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:204–208, 2001

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