Rate constants for reaction of a fluorou
โ
John H. Horner; Felix N. Martinez; Martin Newcomb; Dennis P. Curran
๐
Article
๐
1997
๐
Elsevier Science
๐
French
โ 224 KB
Rate constants for 6-exo cyclization of the 7,7-diphenyl-6-heptenyl radical (3) in benzotrifluoride (BTF, PhCF3) were determined by laser flash photolysis, and radical clock 3 was used in competition kinetic studies for determination of rate constants of reactions of the fluorous tin hydride reagent