Radical reactions of organoaluminium compounds: The reactions fo aluminium triphenyl with benzophenone.
โ Scribed by C. Hrris; T. Mole; F.D. Looney
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 152 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
R.\l)TC IL !II< \C'I' I O'\S o!' C)I~G.\Y(IAI.I'~II NIlY1 COvPoI!sns: TlIE RL\CT roh-OF .\l.l!'rTNrI'M TR I I'lll;YYl: KI'I'II !3ESzo1'1!~~-ONI;: * C .Ilnrris, 'r.vole*and F.l).I,oorlc!y 7s Cl~emical ILesearch I.nl)oratories, C.S. 1 .R.O., I'.~l.llou '1331, G.l'.O., ~lelbournc:,
๐ SIMILAR VOLUMES
Spin-polarized triplet radical pairs produced by the photocbemical reaction of triplet benzophenone \vitb aromatic amines were detected in glassy matrices at 77 I< using a time-resolved ESR method. By analysis of the spectra, it is concluded that the population of the Z spin sublevel of the radical
Fourier transform infrared spectroscopy was used to identify CH2FOOH and HC(O)F as products of the gas-phase reaction of CHIFOz radicals with HOs radicals. At 700 Torr and 295 + 2 K, branching ratios for the CHrFOOH forming channel, k,,/k, =0.29 f 0.08 and the HC(O)F channel, klb/kl =0.71 f 0.11 wer
Arrhenius parameters have been determined for the hydrogen-abstraction reactions: R + SiHCI, + RH + SiCl, CF, 323-46 1 5.98 & 0.06 11.77 f 0.03 8.50 CH, 333-443 4.30 f 0.08 10.83 & 0.04 8.48 C,H, 314-413 5.32 & 0.07 11.54 f 0.04 8.63 7 - l h e trend in activation energies ECH, < E c ~H , < ECF, is