𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Chemiluminescence of organometallic compounds in reactions with the free radical galvinoxyl

✍ Scribed by R. G. Bulgakov

Publisher
Springer
Year
1997
Tongue
English
Weight
139 KB
Volume
46
Category
Article
ISSN
1573-9171

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Molar paramagnetic solvent NMR shifts of
Molar paramagnetic solvent NMR shifts of galvinoxyl in toluene. Kinetics of the reaction between galvinoxyl and tertiary amines at high radical concentrations
✍ Constantinos G. Screttas; Georgios A. Heropoulos πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 373 KB

## Abstract The molar paramagnetic solvent NMR shifts of galvinoxyl (1, Gβ€²) in toluene were measured at 34Β°C and found to be 2.21 and 2.39 ppm mol^βˆ’1^ for the aliphatic and the aromatic proton signals of toluene, respectively. The implications of the inequality of the two molar shifts are discussed

The paramagnetic species produced in the
The paramagnetic species produced in the reactions of organometallic compounds XIIIβ€”the anion radicals of carboxylates
✍ A. StaΕ‘ko; Δ½. Malik; E. Mat'aΕ‘ova; A. TkÑč πŸ“‚ Article πŸ“… 1981 πŸ› John Wiley and Sons 🌐 English βš– 218 KB

## Abstract In the reactions of __meta__‐ and __para__‐alkyl substituted benzoic acids with aryl Grignard reagents, in tetrahydrofuran solutions and in the presence of nickel salts, the ESR spectra of the anion radicals of carboxylates derived from the benzoic acids were observed which represent th

The reactions of transition metal chelat
The reactions of transition metal chelates with organometallic compounds and their paramagnetic products: IVβ€”the anion radical of acetylacetonate
✍ A. StaΕ‘ko; A. TkÑč; V. Laurinc; L. MalΓ­k πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 248 KB

## Abstract The anion radical of acetylacetonate is formed by the reaction of nickel (II) acetylacetonate with Grignard reagents. From the two coupling constants found in the e.s.r. spectrum, the one of 2Β·6 G was assigned to the methine proton and the one of 12Β·5 G to the six equivalent methyl prot