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Radical reactions in synthesis. Homolysis of alkyl cobalt salophens in the presence of radical trapping agents.

✍ Scribed by Vinod F Patel; Gerald Pattenden

Book ID
104227509
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
218 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

Photolytic homolysis of the alkyl cobalt 'salophens' (lo), (205) and (20b) in the presence of radical trapping agents e.g. 02, TEMPO, NO, S02, PhSSPh, PhSeSePh, MeS02C1, BrCC13 and 12, leading to oxygen, nitrogen, sulphur, selenium and halogen functionalised products, is used to demonstrate the versatility of cobaltmediated radical reactions in synthesis.

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