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Radical polymerization reactivity of dialkyl itaconates and characterization of their polymers

โœ Scribed by Takayuki Otsu; Hiroyuki Watanabe

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
538 KB
Volume
29
Category
Article
ISSN
0014-3057

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๐Ÿ“œ SIMILAR VOLUMES

Kinetic and ESR studies on radical polym
Kinetic and ESR studies on radical polymerization. Radical polymerization of diisopropyl itaconate
โœ T. Sato; Y. Hirose; M. Seno; H. Tanaka; N. Uchiumi; M. Matsumoto ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 391 KB

The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be