## Abstract We demonstrated that density functional theory calculations provide a prediction of the trends in CโS bond dissociation energies and atomic spin densities for radicals using two model compounds as diethyldithiocarbamate (DC)โmediated iniferters. On the basis of this information, we synt
Radical polymerization of styrene mediated by 1,3,5-triphenylverdazyl
โ Scribed by Bunichiro Yamada; Yukihiro Nobukane; Yozo Miura
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 538 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0170-0839
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
In an attempt to perform atom transfer radical polymerization (ATRP) with a more environmentally friendly mediator, polymerization of styrene in the presence of iron(II)-chloride and EDTA was explored from a mechanistic point of view. The presence of EDTA, which normally can form a complex with FeCl
## Abstract In the presence of an oligomeric hindered secondary amine added with peracetic acid as the oxidant, radical polymerization of styrene is fast and controlled at 110โยฐC. Under these experimental conditions, an oligomeric nitroxide is formed in situ. This polymerization is 2.5 faster than