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Radical Polymerization Behavior of N-Acryloyl-2,2-dimethyl-5(R)-phenyl-1,3-oxazolidine

✍ Scribed by Seno, Makiko; Takikawa, Tetsuya; Tanaka, Hitoshi; Sato, Tsuneyuki

Book ID
127373993
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
623 KB
Volume
28
Category
Article
ISSN
0024-9297

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(3′S,4R)-3-(3′-Cyclo­pentyl-3′-phenyl­propano­yl)-5,5-dimethyl-4-phenyl-1,3-oxazolidin-2-one
✍ Nie, Lei ;Yang, Rui ;Chen, Jing ;Yan, Sheng-Jiao ;Lin, Jun 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 135 KB

The title compound, C 25 H 29 NO 3 , was prepared from (R)-5,5dimethyl-4-phenyl-3-[(E)-3-phenylacryloyl]oxazolidin-2-one, coupled with cyclopentylmagnesium bromide via asymmetric Michael addition. The relative configuration of the chiral C atoms of the product is as expected.