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Radical mediated intramolecular arylation using tributyltinhydride/aibn: A formal synthesis of steganone

โœ Scribed by N.S Narasimhan; Indraoal Singh Aidhen

Book ID
107858396
Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
128 KB
Volume
29
Category
Article
ISSN
0040-4039

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Cobalt-mediated aryl radical cyclisation
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โœ Andrew J. Clark; Keith Jones ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 567 KB

Abstmct: A synthesis of the te&ahydrofuro[2,3-blindole (3) in 6 step from 4-methoxyaniline involving a key cobalt-mediated aryl radical cycliin is presented. This hetuucycle is a known, late intermediate. in the synthesis of the alkaloid physovenine (2).