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Radical mechanism in the photoreaction of organic N-oxides: oxygen transfer from photoexcited paradiazine di-N-oxides to amines

โœ Scribed by Shu-Kun Lin


Publisher
Elsevier Science
Year
1987
Weight
949 KB
Volume
37
Category
Article
ISSN
0047-2670

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Radical mechanism in the photoreaction o
โœ Shu-Kun Lin ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 320 KB

## Photolysis of benzofurazan N-oxide in chloroform generates the nitroxyl radical l( 3H)-benzofurazanyloxyl via hydrogen abstraction from the solvent molecules by the photoexcited lowest triplet state benzofurazan N-oxide. The photoreaction of benzofurazan N-oxide in triethylamine provides the di