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Radical ions of tert-butylphenylacetylene. Mechanism of their unconventional dimerization and structures of the four isomeric protonated dimers

✍ Scribed by Csuros, Z.; Caluwe, P.; Szwarc, M.


Book ID
127253858
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
607 KB
Volume
95
Category
Article
ISSN
0002-7863

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## Abstract The unimolecular fragmentation reactions of the radical cations of diethyl, diisopropyl, dipropyl, isopropyl propyl, and di(__tert__‐butyl) peroxide have been investigated by mass spectrometric and isotopic labeling techniques. Two competing pathways for unimolecular decomposition in th