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Radical-Initiated, Skeletal Rearrangements of Bicyclo[2.2.2] Lactones

✍ Scribed by Markó, István E.; Warriner, Stuart L.; Augustyns, Benoît


Book ID
126145868
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
51 KB
Volume
2
Category
Article
ISSN
1523-7060

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📜 SIMILAR VOLUMES


Free radical rearrangement of bicyclo[2.
✍ Wei Zhang; Paul Dowd 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 1023 KB

Intramolecular cyclization of carbon radicals to carbonyl groups was carried out on bicydo[2.2.21and bicyclof4.2.Oloctenones. An unexpected ring expansion product 19, produed by /3-scission of the intermediate alkoxyl radical 22, was observed. The j3,ysituated double bond of the bicyclic ketones app

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