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Construction of bicyclo[2.2.2]octane ring system via homoallyl-homoallyl radical rearrangement

✍ Scribed by Masahiro Toyota; Masahiro Yokota; Masataka Ihara


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
226 KB
Volume
40
Category
Article
ISSN
0040-4039

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Free radical rearrangement of bicyclo[2.
✍ Wei Zhang; Paul Dowd πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 1023 KB

Intramolecular cyclization of carbon radicals to carbonyl groups was carried out on bicydo[2.2.21and bicyclof4.2.Oloctenones. An unexpected ring expansion product 19, produed by /3-scission of the intermediate alkoxyl radical 22, was observed. The j3,ysituated double bond of the bicyclic ketones app