Radical gas-phase decomposition of nitrobenzene derivatives
β Scribed by V. G. Matveev; V. V. Dubikhin; G. M. Nazin
- Book ID
- 112439195
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 349 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
It is shown that it is possible to obtain good data for the rate constant for the decomposition 01 alkoxy radicals [RO] by using nitric oxide a s a radical trap. Two experimental systems have been used. T h e first system involves the use of dialkyl peroxides [(RO)?] a s thermal sources ofalkoxy ra
The rate of decomposition of 2-pentoxy radical to acetaldehyde and n-propyl radical has been studied in the presence of NO in competition with nitrite formation at and above 200 kPa pressure over the temperature range of 363-413 K. The rate coefficient for the decomposition is given as log(k,,/s-')