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Radical Cyclizations of Alkenyl Acylphosphonate Derivatives under Thermal and Photochemical Conditions.

โœ Scribed by Chang Ho Cho; Sunggak Kim; Motoki Yamane; Hironori Miyauchi; Koichi Narasaka

Publisher
John Wiley and Sons
Year
2006
Weight
30 KB
Volume
37
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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l-~Telluroglycosides isomenze to or-isomers upon photolysis and thermolysis. The isomerization follows first-order reaction kinetics and proceeds through a glycosyl radical intermediate by homolytic C-Te bond cleavage. The radicals so generated are trapped intermolecularly by TEMPO free radical, ind