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Radical cyclizations of 1,4-dihydropyridines. Synthesis of chiral fused nitrogen heterocycles. Synthesis of lupinine and epilupinine

✍ Scribed by Pierre Mangeney; Louis Hamon; Sabine Raussou; Nicolas Urbain; Alexandre Alexakis


Book ID
104208699
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
952 KB
Volume
54
Category
Article
ISSN
0040-4020

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Radical Cyclizations of 1,4-Dihydropyridines. Synthesis of Chiral Fused Nitrogen Heterocycles. Synthesis of Lupinine and Epilupinine. -A detailed investigation of radical cyclizations of chiral 1,4-dihydropyridines under different reaction conditions is presented. The presence of an aldehyde group

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## Abstract A series of new chiral (__S__)‐3‐ary1‐6‐pyrrolidin‐2‐yl‐[1,2,4]triazolo[3,4‐__b__]thiadiazole (II~1‐5~), (__S__)‐1‐(3‐aryl‐[1,2,4]triazolo[3,4‐__b__][1,3,4]thiadiazol‐6‐yl)‐ethylamine (II~6‐8~) and (__S__)‐1,2‐bis(3‐aryl‐[1,2,4]triazolo‐[3,4‐__b__][1,3,4]thiadiazol‐6‐yl)‐ethylamine (II~