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Radical cyclisation of α,ω-dinitroalkanes

✍ Scribed by W. Russell Bowman; Stuart W. Jackson

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
837 KB
Volume
46
Category
Article
ISSN
0040-4020

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The low-melting isomers of 2,5-dinitro-1,6•hexanedlOl (IB) and 2,6-dinitro-l,7heptanediol (lIB) undergo facile acid-catalyzed epimerization to form the respective highmelting isomers (IA and IIA) in water or in aprotic solvents. The dimethyl ether and bisphenylurethan derivatives of IB are not epime