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Radical cation photoisomerization of bicyclo[2.2.2]octa-2,5-diene to tetracyclo[4.2.0.02,8.05,7]octane and its thermal retrogression

โœ Scribed by Chen, Guo Fei; Pappas, Robert S.; Williams, Ffrancon


Book ID
118734375
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
415 KB
Volume
114
Category
Article
ISSN
0002-7863

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Photoisomerization of bis(perfluoromethy
โœ Robert S.H. Liu ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 173 KB

The reaction of photoisomerization of norbornadiene and its derivatives to the corresponding quardricyclanes, brought about either by direct irradiation or triplet sensitization is well known (1). However, similar isomerizations involving the related bicyclo[2.2.2]octa-2,5-diene system are not known