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Photoisomerization of bis(perfluoromethyl)bicyclo[2.2.2]Octa-2,5-dienes to tetracyclo[4.2.0.02,8.05,7]Octanes

✍ Scribed by Robert S.H. Liu

Book ID: 104239227
Publisher: Elsevier Science
Year: 1969
Tongue: French
Weight: 173 KB
Volume: 10
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)87900-4

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✦ Synopsis

The reaction of photoisomerization of norbornadiene and its derivatives to the corresponding quardricyclanes, brought about either by direct irradiation or triplet sensitization is well known (1). However, similar isomerizations involving the related bicyclo[2.2.2]octa-2,5-diene system are not known. Studies in this area have apparently led to

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