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Radical additions to allyl bromides. A synthetically useful, ‘Tin-Free’ method for carbon–carbon bond formation

✍ Scribed by John A. Struss; Mitra Sadeghipour; James M. Tanko


Book ID
104096349
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
415 KB
Volume
50
Category
Article
ISSN
0040-4039

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Addition of carbon radicals generated from organoselenium reagents P SeR: R= COPh, CO\*Et, CH,CO,Et, CH2COMe, and CH,CN) to 4',5'-unsaturated uraciinucleosides was found to provide a highly efficient entry to C-C bond formation at the 5'-position, the stereochemical outcome of which is dependent upo