Radical Additions of TEMPO to Ketenes: Correlation of Free Radical and Nucleophilic Reactivity
โ Scribed by Allen, Annette D.; Cheng, Bernice; Fenwick, Michael H.; Huang, Wen-wei; Missiha, Sharif; Tahmassebi, Daryoush; Tidwell, Thomas T.
- Book ID
- 120199919
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 83 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1523-7060
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Until now nothing has been recorded on the reactivity of free radicals with nitriloxides, if one excludes the hypothesis of Firestone', which was refuted by
Me = Et > i-Pr & t-Bu"]. I-tert-Butoxy-2,7-octadiene, which was not obtained with conventional catalysts, is also formed. Higher telomers are formed in all cases except with t-BuOH. The presence of large amounts of phenoxy-C,2-derivatives may reflect an alteration in the reaction mechanism. The rea