𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Free radical reactivity of nitriloxides. 1,3-addition.

✍ Scribed by Tullio Caronna; Adolfo Quilico; Francesco Minisci

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
163 KB
Volume
11
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

Until now nothing has been recorded on the reactivity of free radicals with nitriloxides, if one excludes the hypothesis of Firestone', which was refuted by

πŸ“œ SIMILAR VOLUMES

Reactivity of Alkenes in Free-Radical Ad
Reactivity of Alkenes in Free-Radical Additions
✍ Priv.-Doz. Dr. Bernd Giese; Dipl.-Chem. Wolfgang Zwick πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 237 KB πŸ‘ 2 views
Free radical addition of 1,3,5 - trioxan
Free radical addition of 1,3,5 - trioxan to olefins
✍ I. Rosenthal πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 78 KB

In a recent publication (1) we have reported the light-induced addition of acetals to olefins which led to the corresponding monoalkyl acetal derivatives. We report now the peroxide-induced addition of 1.3,5-trioxan to olefins at elevated temperatures.

Which Factors Determine the Reactivity a
Which Factors Determine the Reactivity and Regioselectivity of Free Radical Substitution and Addition Reactions?
✍ Prof. Dr. John M. Tedder πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 886 KB

## Abstract The relative importance of bond strength, steric effects, and polarity in determining the rate and orientation of free radical subsitution and free radical addition reaction is considered. The factors which control substitution reaction (radical transfer reaction) are gathered together